Suzuki coupling approach for the synthesis of phenylene-pyrimidine alternating oligomers for blue light-emitting material.

نویسندگان

  • Ken-Tsung Wong
  • Tsung Shi Hung
  • Yuting Lin
  • Chung-Chih Wu
  • Gene-Hsiang Lee
  • Shie-Ming Peng
  • Chung Hsien Chou
  • Yuhlong Oliver Su
چکیده

[reaction: see text] Conjugated oligomers with an alternating phenylene-pyrimidine structure have been synthesized by the successive Suzuki coupling reaction starting from 2-bromo-5-iodopyrimidine. The photoluminescence properties and quasi-reversible redox behavior of these oligomers make them applicable as an active material for a light-emitting device. Blue light-emitting electroluminescent devices with an external quantum efficiency up to 1.8% have been fabricated.

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عنوان ژورنال:
  • Organic letters

دوره 4 4  شماره 

صفحات  -

تاریخ انتشار 2002